When you change the IP of an "inner" mail server. You need to perform the following:

  1. Change /etc/postfix/transport (to send the mail to the right server)
  2. Change /etc/postfix/mynetworks (to be able to forward mail from your new IP)
  3. postmap transport //Compiles the transport file into transport.db - you don't need to do this for mynetworks

Concepts: